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  8. Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine, 97%, maycontain suspended amine hydrochloride crystals

Product Code. 11495620
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Product Code. 11495620 Supplier Thermo Scientific Alfa Aesar Supplier No. H25883.03
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Description

CAS: 142421-57-6 | C16H6ClF12P | 492.629 g/mol

Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine is used as a reactant for the synthesis of chiral phosphine-aminophosphine ligands for rhodium-catalyzed asymmetric hydrogenation, ligands for palladium-catalyzed stereoselective allylation reactions, enantioselective hydrogenations, Josiphos analog as catalyst for asymmetric hydrogenation, ligands used in asymmetric hydrovinylation reactions.

Solubility
Reacts with water.

Notes
Air & moisture sensitive. Store away from oxidizing agents, bases, air, water/ moisture.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 142421-57-6
Molecular Formula C16H6ClF12P
Molecular Weight (g/mol) 492.629
MDL Number MFCD01630852
InChI Key DFZQEHBNAJGDCT-UHFFFAOYSA-N
Synonym bis 3,5-di trifluoromethyl phenyl chlorophosphine, phosphinous chloride, bis 3,5-bis trifluoromethyl phenyl, acmc-20alnu, bis 3,5-bis trifluoromethyl phenyl chlorophosphine, bis 3,5-bis trifluoromethyl phenyl-chlorophosphane, bis 3,5-bis trifluoromethyl phenyl-chlorophosphine, bis 3,5-bis trifluoromethyl phenyl chloro phosphane, p,p-bis 3,5-bis trifluoromethyl phenyl phosphinous chloride, phosphinous chloride,p,p-bis 3,5-bis trifluoromethyl phenyl
PubChem CID 5104965
IUPAC Name bis[3,5-bis(trifluoromethyl)phenyl]-chlorophosphane
SMILES C1=C(C=C(C=C1C(F)(F)F)P(C2=CC(=CC(=C2)C(F)(F)F)C(F)(F)F)Cl)C(F)(F)F

Specifications

Quantity 1 g
UN Number UN3265
Sensitivity Air and moisture sensitive; May form a precipitate
Solubility Information Reacts with water.
Formula Weight 492.63
Percent Purity ≥98%
Assay may contain suspended dimethylamine hydrochloride crystals
Chemical Name or Material Chlorobis[3,5-bis(trifluoromethyl)phenyl]phosphine

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