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tert-Butyl hydroperoxide, 70% aq. soln., Thermo Scientific Chemicals

Catalog Number 11461648
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Quantity:
100 mL
500 mL
2500 mL
This item is not returnable. View return policy
To receive the discount customers must purchase three of the same product at list price in a single order to receive 33.33% discount. There is no limit to the multiples of 3 that customers can buy. Use promo code ”21615” to get your promotional price
75-91-2
C4H10O2
90.122
MFCD00002130
CIHOLLKRGTVIJN-UHFFFAOYSA-N
tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid
6410
CHEBI:64090
2-hydroperoxy-2-methylpropane
CC(C)(C)OO
This item is not returnable. View return policy
To receive the discount customers must purchase three of the same product at list price in a single order to receive 33.33% discount. There is no limit to the multiples of 3 that customers can buy. Use promo code ”21615” to get your promotional price
75-91-2
C4H10O2
90.122
MFCD00002130
CIHOLLKRGTVIJN-UHFFFAOYSA-N
tert-butyl hydroperoxide, tbhp, t-butyl hydroperoxide, tert-butylhydroperoxide, perbutyl h, t-butylhydroperoxide, cadox tbh, hydroperoxide, 1,1-dimethylethyl, 1,1-dimethylethyl hydroperoxide, terc. butylhydroperoxid
6410
CHEBI:64090
2-hydroperoxy-2-methylpropane
CC(C)(C)OO

tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
tert-Butyl hydroperoxide is used as an initiator for radical polymerization and in various oxidation process such as sharpless epoxidation. It is involved in osmium catalyzed vicinal hydroxylation of olefins under alkaline conditions. Furthermore, it is used in catalytic asymmetric oxidation of sulfides to sulfoxides using binaphthol as a chiral auxiliary and in the oxidation of dibenzothiophenes. It plays an important role for the introduction of peroxy groups in organic synthesis.

Solubility
Miscible with water and diethyl ether.

Notes
Light sensitive. Store in cool place. Incompatible with powdered metals, strong oxidizing agents, reducing agents, acids, alkalis and heavy metals.
TRUSTED_SUSTAINABILITY
Melting Point °C to 3°C
Density 0.937
Boiling Point 96°C (decomposition)
Flash Point 43°C (109°F)
Assay Percent Range 70% Aqueous Solution
Linear Formula (CH3)3COOH
Refractive Index 1.387
Quantity 500 mL
UN Number UN3109
Beilstein 1098280
Merck Index 14,1570
Solubility Information Miscible with water and diethyl ether.
Formula Weight 90.12
Chemical Name or Material tert-Butyl Hydroperoxide
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Hazard Category
  • Carcinogenicity Category 2
  • Skin sensitiser Category 1
Hazard Statement
  • H331-Toxic if inhaled.
  • H351-Suspected of causing cancer.

RUO – Research Use Only

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