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  8. (R)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene, Thermo Scientific Chemicals

(R)-2-Methyl-CBS-oxazaborolidine, 1M soln. in toluene, Thermo Scientific Chemicals

Catalog Number 11373596
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Quantity:
1 mL
5 mL
25 mL
This item is not returnable. View return policy
112022-83-0
C18H20BNO
277.17
MFCD00078440
VMKAFJQFKBASMU-QGZVFWFLSA-N
r-2-methyl-cbs-oxazaborolidine, r-methyl oxazaborolidine, r-+-2-methyl-cbs-oxazaborolidine, r-5,5-diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, r-1-methyl-3,3-diphenylhexahydropyrrolo 1,2-c 1,3,2 oxazaborole, r-me-cbs catalyst, r-3,3-diphenyl-1-methylpyrrolidino 1,2-c-1,3,2-oxazaborole, r-me cbs, r-tetrahydro-1-methyl-3,3-diphenyl-1h,3h-pyrrolo 1,2-c 1,3,2 oxazaborole, corey's catalyst
9838490
(3aR)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
[H][C@]12CCCN1B(C)OC2(C1=CC=CC=C1)C1=CC=CC=C1
This item is not returnable. View return policy
112022-83-0
C18H20BNO
277.17
MFCD00078440
VMKAFJQFKBASMU-QGZVFWFLSA-N
r-2-methyl-cbs-oxazaborolidine, r-methyl oxazaborolidine, r-+-2-methyl-cbs-oxazaborolidine, r-5,5-diphenyl-2-methyl-3,4-propano-1,3,2-oxazaborolidine, r-1-methyl-3,3-diphenylhexahydropyrrolo 1,2-c 1,3,2 oxazaborole, r-me-cbs catalyst, r-3,3-diphenyl-1-methylpyrrolidino 1,2-c-1,3,2-oxazaborole, r-me cbs, r-tetrahydro-1-methyl-3,3-diphenyl-1h,3h-pyrrolo 1,2-c 1,3,2 oxazaborole, corey's catalyst
9838490
(3aR)-1-methyl-3,3-diphenyl-3a,4,5,6-tetrahydropyrrolo[1,2-c][1,3,2]oxazaborole
[H][C@]12CCCN1B(C)OC2(C1=CC=CC=C1)C1=CC=CC=C1

Description

(R)-2-Methyl-CBS-oxazaborolidine is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols. It is also used in a desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone. It is useful in the production of stereospecific motifs such as α-hydroxy acids, α-amino acids, symmetrical ferrocenyl diols and propargyl alcohols.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
(R)-2-Methyl-CBS-oxazaborolidine is used in the asymmetric reduction of prochiral ketones. Other applications include the enantioselective synthesis of α-hydroxy acids, α-amino acids, C2 symmetrical ferrocenyl diols, and propargyl alcohols. It is also used in a desymmetrizing reduction leading to (S)-4-hydroxycyclohexenone. It is useful in the production of stereospecific motifs such as α-hydroxy acids, α-amino acids, symmetrical ferrocenyl diols and propargyl alcohols.

Solubility
Not miscible or difficult to mix in water.

Notes
Store in cool place. Keep container tightly closed in a dry and well-ventilated place. Containers which are opened must be carefully resealed and kept upright to prevent leakage. Store under inert gas. It is sensitive to moisture and air. Incompatible with oxidizing agents.
TRUSTED_SUSTAINABILITY
Density 0.925
Flash Point 4°C (39°F)
Quantity 25 mL
UN Number UN1993
Sensitivity Air and moisture sensitive
Solubility Information Not miscible or difficult to mix in water.
Formula Weight 277.17
Concentration or Composition (by Analyte or Components) 1M soln. in toluene
Chemical Name or Material (R)-2-Methyl-CBS-oxazaborolidine

RUO – Research Use Only

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