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  8. Benzhydryl bromide, 90+%, Thermo Scientific Chemicals

Benzhydryl bromide, 90+%, Thermo Scientific Chemicals

Catalog Number 11351547
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Quantity:
25 g
100 g
500 g
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776-74-9
C13H11Br
247.135
MFCD00000134
OQROAIRCEOBYJA-UHFFFAOYSA-N
bromodiphenylmethane, benzhydryl bromide, diphenylmethyl bromide, diphenylbromomethane, alpha-bromodiphenylmethane, bromo phenyl methyl benzene, benzene, 1,1'-bromomethylene bis, methane, bromodiphenyl, bromomethylene dibenzene, bromodiphenyl methane
236603
[bromo(phenyl)methyl]benzene
C1=CC=C(C=C1)C(C2=CC=CC=C2)Br
This item is not returnable. View return policy
776-74-9
C13H11Br
247.135
MFCD00000134
OQROAIRCEOBYJA-UHFFFAOYSA-N
bromodiphenylmethane, benzhydryl bromide, diphenylmethyl bromide, diphenylbromomethane, alpha-bromodiphenylmethane, bromo phenyl methyl benzene, benzene, 1,1'-bromomethylene bis, methane, bromodiphenyl, bromomethylene dibenzene, bromodiphenyl methane
236603
[bromo(phenyl)methyl]benzene
C1=CC=C(C=C1)C(C2=CC=CC=C2)Br

Description

Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
Benzhydryl bromide is a halogenated building block. Benzhydryl group was preferred to the commoner benzyl to protect 2-nitrophenol in the Bartoli (vinyl Grignard) synthesis of 7-hydroxyindole. Protection was by reaction with the phenol in the presence of potassium carbonate in acetone; deprotection of the indole was by hydrogenolysis.

Solubility
Insoluble in water.

Notes
Keep container tightly sealed. Store in cool, dry conditions in well sealed containers. Incompatible with oxidizing agents and bases. It is sensitive to moisture. Protect from humidity and water. Store under dry inert gas.
TRUSTED_SUSTAINABILITY
Melting Point 36°C to 41°C
Boiling Point 183°C to 185°C (20 mmHg)
Flash Point >110°C (230°F)
Odor Pungent
Quantity 25 g
UN Number UN1770
Beilstein 638544
Sensitivity Moisture sensitive
Solubility Information Insoluble in water.
Formula Weight 247.14
Percent Purity ≥90%
Chemical Name or Material Benzhydryl bromide
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