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  7. 9-BBN monomer, 97%, 0.5M in THF, Thermo Scientific™

9-BBN monomer, 97%, 0.5M in THF, Thermo Scientific™

Product Code. 15438907
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Product Code. 15438907 Supplier Thermo Scientific Alfa Aesar Supplier No. H52287.AP
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Description

This Thermo Scientific brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific.

Applications
9-BBN monomer acts as a selective hydroboration reagent in synthetic organic chemistry. It is employed in Suzuki reactions as well as in the preparation of terminal alcohols by the region selective addition of alkenes followed by oxidative cleavage using hydrogen peroxide. It is also used in copper-catalyzed cross-coupling reactions of organoboron compounds with primary alkyl halides and pseudohalides. It acts as a protecting group for alkenes. Further, it is used as a reactant for Hetero-Diels-Alder reaction for the synthesis of spirocyclic alkaloids. In addition to this, it is used in intramolecular insertion of alkenes into palladium-nitrogen bonds.

Solubility
Miscible with ether, hexane, benzene, toluene, carbon tetrachloride, chloroform, dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane, dimethoxyethane, diglyme and dioxane.

Notes
Air and moisture sensitive. Keep the container tightly closed in a dry and well-ventilated place. Incompatible with water, oxidizing agents, acids and alcohols.
TRUSTED_SUSTAINABILITY

Chemical Identifiers

CAS 280-64-8
Molecular Formula C8H14B
Molecular Weight (g/mol) 121.01
MDL Number MFCD00074742
InChI Key AMKGKYQBASDDJB-UHFFFAOYSA-N
Synonym 9-borabicyclo 3.3.1 nonane, 9-borabicyclo 3.3.1 nonan, 9-borabicyclo 3,3,1 nonane, 9$l^ 2-borabicyclo 3.3.1 nonane, 1s,5s-9-borabicyclo 3.3.1 nonane, monomer; 21205-91-4 dimer, 9-borabicyclo 3.3.1 nonane,9-bbn,intetrahydrofuran
PubChem CID 6327450
IUPAC Name 9$l^{2}-borabicyclo[3.3.1]nonane
SMILES [B]1C2CCCC1CCC2

Specifications

Flash Point −19°C (−2°F)
Odor Ether-like
Quantity 500 mL
UN Number UN3399
Beilstein 605509
Sensitivity Air and moisture sensitive
Solubility Information Miscible with ether,hexane,benzene,toluene,carbon tetrachloride,chloroform,dimethylsulfide and dichloromethane. Slightly miscible with cyclohexane,dimethoxyethane,diglyme and dioxane.
Formula Weight 122.02
Percent Purity 97%
Concentration or Composition (by Analyte or Components) 0.5M in THF
Chemical Name or Material 9-BBN monomer
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