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  7. 4-(Methoxycarbonyl)benzeneboronic acid, 97%

4-(Methoxycarbonyl)benzeneboronic acid, 97%

Product Code. 11486570
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Product Code. 11486570 Supplier Thermo Scientific Alfa Aesar Supplier No. H27627.06
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Beskrivning

CAS: 99768-12-4 | C8H9BO4 | 179.966 g/mol

It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

This Thermo Scientific Chemicals brand product was originally part of the Alfa Aesar product portfolio. Some documentation and label information may refer to the legacy brand. The original Alfa Aesar product / item code or SKU reference has not changed as a part of the brand transition to Thermo Scientific Chemicals.

Applications
It is a reagent used for tandem-type Pd(II)-catalyzed oxidative Heck reaction and intramolecular C-H amidation sequence, copper-mediated ligandless aerobic fluoroalkylation of arylboronic acids with fluoroalkyl iodides, one-pot ipso-nitration of arylboronic acids, copper-catalyzed nitration and cyclocondensation followed by palladium-phosphine-catalyzed Suzuki-Miyaura coupling. It is employed as reagent in Reagent used in preparation of biaryls via nickel-catalyzed Suzuki-Miyaura cross-coupling reaction of aryl halides with arylboronic acid, chromenones and their bradykinin B1 antagonistic activity, Pt nanoparticles on Photoactive metal-organic frameworks resulting in efficient hydrogen evolution via synergistic photoexcitation and electron injection and salicylate-based thienylbenzoic acids as E. coli methionine aminopeptidase inhibitor.

Solubility
Soluble in methanol.

Notes
Store in cool dry conditions. Incompatible with oxidizing agents. Ensure good ventilation.
TRUSTED_SUSTAINABILITY

Kemiska identifierare

CAS 99768-12-4
Molecular Formula C8H9BO4
Molecular Weight (g/mol) 179.966
MDL Number MFCD01632203
InChI Key PQCXFUXRTRESBD-UHFFFAOYSA-N
Synonym methyl 4-boronobenzoate, 4-methoxycarbonyl phenylboronic acid, 4-methoxycarbonyl phenyl boronic acid, 4-methoxycarbonyl benzeneboronic acid, 4-methoxycarbonylphenyl boronic acid, methyl4-boronobenzoate, 4-methoxycarbonylbenzeneboronic acid, p-methoxycarbonyl phenylboronic acid, 4-methoxycabonyl phenylboronic acid
PubChem CID 2734369
IUPAC Name (4-methoxycarbonylphenyl)boronic acid
SMILES B(C1=CC=C(C=C1)C(=O)OC)(O)O

Specifikationer

Melting Point 220°C to 225°C
Quantity 5 g
Solubility Information Soluble in methanol.
Formula Weight 179.97
Percent Purity 97%
Chemical Name or Material 4-(Methoxycarbonyl)benzeneboronic acid

Säkerhet och hantering

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Produktbeteckning
  • 4-(Methoxycarbonyl)benzeneboronic acid
 Signalord
  • Warning
 Riskkategorier
  • Serious eye damage/eye irritation Category 2
  • Skin corrosion/irritation Category 2
  • Specific target organ toxicity Category 3
 Faroangivelser
  • H315-Causes skin irritation.
  • H319-Causes serious eye irritation.
  • H335-May cause respiratory irritation.
 Skyddsangivelse
  • P261-Avoid breathing dust/fume/gas/mist/vapours/spray.
  • P280-Wear protective gloves/protective clothing/eye protection/face protection.
  • P302+P352-IF ON SKIN: Wash with plenty of water/soap.
  • P305+P351+P338-IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing.
 Kompletterande information
  • MIXTURE LIST-Contain: 4-(Methoxycarbonyl)benzeneboronic acid
SDS

RUO – Research Use Only

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